Crystal structure of trans-diacetonitrile diaqua(N,N,N',N'-tetramethylethylenediamine) nickel(II) diiodide, [Ni(tmen)(CH3CN)2(H2O)2]2+·2I–, C10H26I2N4NiO2
نویسندگان
چکیده
منابع مشابه
Crystal structure of poly[[trans-diaquabis[μ2-trans-4,4′-(diazenediyl)dipyridine]nickel(II)] diiodide ethanol disolvate]
In the title compound, {[Ni(C10H8N4)2(H2O)2]I2·2C2H5OH} n , the complex shows an octa-hedral environment of the Ni(2+) cation in which it is located on a centre of symmetry, linked to two water mol-ecules and the pyridine-N atoms of four 4,4'-(diazenediyl)dipyridine ligands bridging Ni(2+) cations along the b- and c-axis directions, giving rise to a two-dimensional arrangement. The Ni-N bond le...
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1,4-diazoniabicyclo[2.2.2]octane diiodide monohydrate was synthesized by protonation of 1,4-diazabicyclo[2.2.2]octane (DABCO) with an excess of concentrated hydroiodic acid in water. It forms colourless rodlike crystals. At room temperature an orthorhombic unit cell, space group Cmc21, a 1⁄4 7.781(2) Å, b 1⁄4 13.010(3) Å, c 1⁄4 11.610(2) Å, V 1⁄4 1175.3(4) Å3, Z 1⁄4 4, is observed. Both nitroge...
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The asymmetric unit of the title salt, [Mn(C2H6OS)6]I2, consists of one Mn(II) ion, six O-bound dimethyl sulfoxide (DMSO) ligands and two I(-) counter-anions. The isolated complex cations have an octa-hedral configuration and are grouped in hexa-gonally arranged rows extending parallel to [100]. The two I(-) anions are located between the rows and are linked to the cations through two weak C-H⋯...
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The new trans-[Pt(4-mpy)2Cl4] (1) complex (4-mpy is 4-methylpyridine) was prepared from the reaction of H2PtCl6.6H2O with 4-methylpyridine in methanol. Synthesized complex was thoroughly characterized by elemental analysis, IR and 1H-NMR spectroscopy.Elemental analysis data (C, H, N) support the general composition of the title complex and the structure have been established by single-crystal X...
متن کاملCrystal structure of trans-dibromobis(triphenylphosphine)platinum(II).
Crystal structure of trans-dibromobis(triphenylphosphine)platinum(II) was determined by X-ray-crystallography. The complex crystallizes on an inversion center in distorted square planar coordination around platinum with triphenylphosphine ligands in trans positions to each other and with two molecules of dichloromethane as solvate.
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ژورنال
عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures
سال: 2013
ISSN: 2197-4578,1433-7266
DOI: 10.1524/ncrs.2013.0049